New Ferrocene Derivatives for Ligand Grafting
نویسندگان
چکیده
منابع مشابه
A Ferrocene-Porphyrin Ligand for Multi-Transduction Chemical Sensor Development
5,10,15,20-Tetraferrocenyl porphyrin, H2TFcP, a simple example of a donor-acceptor system, was tested as ligand for the development of a novel multi-transduction chemical sensors aimed at the determination of transition metal ions. The fluorescence energy transfer between ferrocene donor and porphyrin acceptor sub-units was considered. The simultaneously measured optical and potentiometric resp...
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1,1 0-Ferrocene dicarboxylic acid pyridin-4-yl ester (1) is prepared from 1,1 0-ferrocene dicarbonyl chloride and 4-hydroxypyridine. This new bidentate ferrocenoyl ligand reacts with the monocationic complex [(g-p-cymene)2Ru2(l-OH)3] + to give the dicationic complex [(g-p-cymene)2Ru2(l-OH)2(1,1 0(NC5H4–OOC)2–Fc)] 2+ (2) (Fc: C5H4–Fe–C5H4), isolated as a tetrafluoroborate salt. The single-crysta...
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Reactions of N-isocyaniminotriphenylphosphorane with a cyclic ketone in the presence of ferrocene carboxylic acid proceeded smoothly at room temperature and in neutral conditions to afford ferrocene-containing 1,3,4-oxadiazole derivatives in high yields. The reaction proceeded smoothly and cleanly under mild conditions and no side reactions were observed. The structures of the products were ded...
متن کاملCucurbit[7]uril-included neutral intramolecular charge-transfer ferrocene derivatives.
CB[7] can significantly modulate the intramolecular charge-transfer state of the designed ferrocene derivatives, resulting in remarkable changes in the absorption spectra, (1)H NMR spectra and electrochemical properties.
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An ortho-metalation method for free ferrocenyl alcohols has been developed, which allows preparation of planar chiral ferrocene derivatives with high yields and diastereoselectivities.
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ژورنال
عنوان ژورنال: French-Ukrainian Journal of Chemistry
سال: 2015
ISSN: 2312-3222
DOI: 10.17721/fujcv3i2p131-139